Syredissociationskonstanter for Organiske forbindelser
Den følgende tabel, giver pKa og Ka værdierne for udvalgte svage syrer. Alle værdierne kommer fra Martell, A. E.; Smitg, R. M. Critical Stability Constants, volumen 1-4. Plenum Press: New York, 1976. Med mindre andet er angivet, er værdierne angivet ved 25 °C og nul ionisk styrke. Værdierne i kantede parenteser, anses for mindre pållidelige.
Svage syrer, arrangeres alfabetisk ved navnene på de neutrale forbindelser, hvorfra de stammer. I nogle tilfælde – som for eksempel eddikesyre – er forbindelsen den svage syre. I andre tilfælde – som for eksempel ammoniumionen – er den neutrale forbindelse den korresponderende base. Kemiske formler eller strukturformler, er vist for det fuldstændigt protonerede svage syre. På hinanden følgende syredissociationskonstanter, er vist for polyprotiske svage syrer; hvor der er tvetydighed, er den specifikke syreproton identificeret.
For at finde Kb værdien for en korresponderende svag base, så husk at:
Ka · Kb = Kw
for en korresponderende svag syre, HA, og dens korresponderende svage base, A–
Forbindelse | Korresponderende syre |
pKa | Ka |
Eddikesyre | CH3COOH | 4.757 | 1.75×10–5 |
Adipinsyre | ![]() |
4.42 5.42 | 3.8×10–5 3.8×10–6 |
Alanin | ![]() |
2.348 (COOH) 9.867 (NH3) | 4.49×10–3 1.36×10–10 |
Aminobenzen | ![]() |
4.601 | 2.51×10–5 |
4-aminobenzensulfonsyre | ![]() |
3.232 | 5.86×10–4 |
2-aminobenzoesyre | ![]() |
2.08 (COOH) 4.96 (NH3) | 8.3×10–3 1.1×10–5 |
2-aminophenol (T = 20 oC) | ![]() |
4.78 (NH3) 9.97 (OH) | 1.7×10–5 1.05×10–10 |
Ammonium | NH4+ | 9.244 | 5.70×10–10 |
Arginin | ![]() |
1.823 (COOH) 8.991 (NH3) [12.48] (NH2) | 1.50×10–2 1.02×10–9 [3.3×10–13] |
Arsensyre | H3AsO4 | 2.24 6.96 11.50 |
5.8×10–3 1.1×10–7 3.2×10–12 |
Asparagin (μ = 0.1 M) | ![]() |
2.14 (COOH) 8.72 (NH3) |
7.2×10–3 1.9×10–9 |
Asparaginsyre | ![]() |
1.990 (α-COOH) 3.900 (β-COOH) 10.002 (NH3) |
1.02×10–2 1.26×10–4 9.95×10–11 |
Benzoesyre | ![]() |
4.202 | 6.28×10–5 |
Benzylamin | ![]() |
9.35 | 4.5×10–10 |
Borsyre (pKa2, pKa3:T = 20 oC) | H3BO3 | 9.236 [12.74] [13.80] |
5.81×10–10 [1.82×10–13] [1.58×10–14] |
Kulsyre | H2CO3 | 6.352 10.329 |
4.45×10–7 4.69×10–11 |
Catechol | ![]() |
9.40 12.8 |
4.0×10–10 1.6×10–13 |
Chloreddikesyre | ClCH2COOH | 2.865 | 1.36×10–3 |
Chromsyre (pKa1:T = 20 oC) | H2CrO4 | -0.2 6.51 |
1.6 3.1×10–7 |
Citronsyre | ![]() |
3.128 (COOH) 4.761 (COOH) 6.396 (COOH) |
7.45×10–4 1.73×10–5 4.02×10–7 |
Cupferron (μ = 0.1 M) | ![]() |
4.16 | 6.9×10–5 |
Cystein | ![]() |
[1.71] (COOH) 8.36 (SH) 10.77 (NH3) |
[1.9×10–2] 4.4×10–9 1.7×10–11 |
Dichloreddikesyre | Cl2CHCOOH | 1.30 | 5.0×10–2 |
Duethylamin | (CH3CH2)2NH2+ | 10.933 | 1.17×10–11 |
Dimethylamin | (CH3)2NH2+ | 10.774 | 1.68×10–11 |
Dimethylglyoxim | ![]() |
10.66 12.0 |
2.2×10–11 1.×10–12 |
Ethylamin | CH3CH2NH3+ | 10.636 | 2.31×10–11 |
Ethylendiamin | +H3NCH2CH2NH3+ | 6.848 9.928 |
1.42×10–7 1.18×10–10 |
Ethylendiamintetraeddikesyre (EDTA) (μ = 0.1 M) | ![]() |
0.0 (COOH) 1.5 (COOH) 2.0 (COOH) 2.66 (COOH) 6.16 (NH) 10.24 (NH) |
1.0 3.2×10–2 1.0×10–2 2.2×10–3 6.9×10–7 5.8×10–11 |
formic acidMyresyre | HCOOH | 3.745 | 1.80×10–4 |
Fumarsyre | ![]() |
3.053 4.494 |
8.85×10–4 3.21×10–5 |
Glutaminsyre | ![]() |
2.33 (α-COOH) 4.42 (λ-COOH) 9.95 (NH3) |
5.9×10–3 3.8×10–5 1.12×10–10 |
Glutamin (μ = 0.1 M) | ![]() |
2.17 (COOH) 9.01 (NH3) |
6.8×10–3 9.8×10–10 |
Glycin +H3NCH2COOH | ![]() |
2.350 (COOH) 9.778 (NH3) |
4.47×10–3 1.67×10–10 |
Glycolsyre | HOOCH2COOH | 3.831 (COOH) | 1.48×10–4 |
Histidin (μ = 0.1 M) | ![]() |
1.7 (COOH) 6.02 (NH) 9.08 (NH3) |
2.×10–2 9.5×10–7 8.3×10–10 |
Hydrogencyanid | HCN | 9.21 | 6.2×10–10 |
Hydrogenfluorid | HF | 3.17 | 6.8×10–4 |
Hydrogenperoxid | H2O2 | 11.65 | 2.2×10–12 |
Hydrogensulfid | H2S | 7.02 13.9 |
9.5×10–8 1.3×10–14 |
Hydrogenthiocyanat | HSCN | 0.9 | 1.3×10–1 |
8-hydroxyquinolin | ![]() |
4.91 (NH) 9.81 (OH) |
1.2×10–5 1.6×10–10 |
Hydroxylamin | HONH3+ | 5.96 | 1.1×10–6 |
Hypobromsyre | HOBr | 8.63 | 2.3×10–9 |
Hypochlorsyre | HOCl | 7.53 | 3.0×10–8 |
Hypoiodsyre | HOI | 10.64 | 2.3×10–11 |
Iodsyre | HIO3 | 0.77 | 1.7×10–1 |
Isoleucin | ![]() |
2.319 (COOH) 9.754 (NH3) |
4.80×10–3 1.76×10–10 |
Leucin | ![]() |
2.329 (COOH) 9.747 (NH3) |
4.69×10–3 1.79×10–10 |
Lysin (μ = 0.1 M) | ![]() |
2.04 (COOH) 9.08 (α-NH3) 10.69 (ε-NH3) |
9.1×10–3 8.3×10–10 2.0×10–11 |
Maleinsyre | ![]() |
1.910 6.332 |
9.1×10–3 9.1×10–3 |
Æblesyre | ![]() |
3.459 (COOH) 5.097 (COOH) |
9.1×10–3 9.1×10–3 |
Malonsyre | HOOCCH2COOH | 2.847 5.696 |
9.1×10–3 9.1×10–3 |
Methionin (μ = 0.1 M) | ![]() |
2.20 (COOH) 9.05 (NH3) |
9.1×10–3 9.1×10–3 |
Methylamin | CH3NH3+ | 10.64 | 9.1×10–3 |
2-methylanalin | ![]() |
4.447 | 9.1×10–3 |
4-methylanaline | ![]() |
5.084 | 9.1×10–3 |
2-methylphenol | ![]() |
10.28 | 9.1×10–3 |
4-methylphenol | ![]() |
10.26 | 9.1×10–3 |
Nitrilotrieddikesyre (T = 20 oC) (pKa1: μ = 0.1 m) | ![]() |
1.1 (COOH) 1.650 (COOH) 2.940 (COOH) 10.334 (NH3) |
9.1×10–3 9.1×10–3 9.1×10–3 9.1×10–3 |
2-nitrobenzoesyre | ![]() |
2.179 | 9.1×10–3 |
3-nitrobenzoesyre | ![]() |
3.449 | 9.1×10–3 |
4-nitrobenzoesyre | ![]() |
3.442 | 3.61×10–4 |
2-nitrophenol | ![]() |
7.21 | 6.2×10–8 |
3-nitrophenol | ![]() |
8.39 | 4.1×10–9 |
4-nitrophenol | ![]() |
7.15 | 7.1×10–8 |
Salpetersyrling | HNO2 | 3.15 | 7.1×10–4 |
Oxalsyre | H2C2O4 | 1.252 4.266 |
5.60×10–2 5.42×10–5 |
1,10-phenanthrolin | ![]() |
4.86 | 1.38×10–5 |
Phenol | ![]() |
9.98 | 1.05×10–10 |
Phenylalanin | ![]() |
2.20 (COOH) 9.31 (NH3) |
6.3×10–3 4.9×10–10 |
Phosphorsyre | H3PO4 | 2.148 7.199 12.35 |
7.11×10–3 6.32×10–8 4.5×10–13 |
phthalsyre | ![]() |
2.950 5.408 |
1.12×10–3 3.91×10–6 |
Piperidin | ![]() |
11.123 | 7.53×10–12 |
Prolin | ![]() |
1.952 (COOH) 10.640 (NH) |
1.12×10–2 2.29×10–11 |
Propansyre | CH3CH2COOH | 4.874 | 1.34×10–5 |
Propylamin | CH3CH2CH2NH3+ | 10.566 | 2.72×10–11 |
Pyridin | ![]() |
5.229 | 5.90×10–6 |
Resorcinol | ![]() |
9.30 11.06 |
5.0×10–10 8.7×10–12 |
Salicylsyre | ![]() |
2.97 (COOH) 13.74 (OH) |
1.1×10–3 1.8×10–14 |
Serin | ![]() |
2.187 (COOH) 9.209 (NH3) |
6.50×10–3 6.18×10–10 |
Ravsyre | ![]() |
4.207 5.636 |
6.21×10–5 2.31×10–6 |
Svovlsyre | H2SO4 | strong 1.99 |
— 1.0×10–2 |
Svovlsyrling | H2SO3 | 1.91 7.18 |
1.2×10–2 6.6×10–8 |
D-vinsyre | ![]() |
3.036 (COOH) 4.366 (COOH) |
9.20×10–4 4.31×10–5 |
Threonin | ![]() |
2.088 (COOH) 9.100 (NH3) |
8.17×10–3 7.94×10–10 |
Thiosvovlsyre | H2S2O3 | 0.6 1.6 |
3.×10–1 3.×10–2 |
Trichloreddikesyre (μ = 0.1 M) | Cl3CCOOH | 0.66 | 2.2×10–1 |
Triethanolamin | (HOCH2CH2)3NH+ | 7.762 | 1.73×10–8 |
Triethylamin | (CH3CH2)3NH+ | 10.715 | 1.93×10–11 |
Trimethylamin | (CH3)3NH+ | 9.800 | 1.58×10–10 |
tris(hydroxymethyl)aminomethan (TRIS or THAM) | (HOCH2)3CNH3+ | 8.075 | 8.41×10–9 |
Tryptophan (μ = 0.1 M) | ![]() |
2.35 (COOH) 9.33 (NH3) |
4.5×10–3 4.7×10–10 |
Tyrosin (pKa1: μ = 0.1 M) | ![]() |
2.17 (COOH) 9.19 (NH3) 10.47 (OH) |
6.8×10–3 6.5×10–10 3.4×10–11 |
Valin | ![]() |
2.286 (COOH) 9.718 (NH3) |
5.18×10–3 1.91×10–10 |